High yield synthesis and structures of some achiral and chiral (diphosphine)tetracarbonylchromium(0) chelate complexes with tetracarbonyl(norbornadiene)chromium(0) as complexation reagent

Markus Strotmann; Rudolf Wartchow; Holger Butenschön

High yield synthesis and structures of some achiral and chiral (diphosphine)tetracarbonylchromium(0) chelate complexes with tetracarbonyl(norbornadiene)chromium(0) as complexation reagent

Markus Strotmann, Rudolf Wartchow, Holger Butenschön^*

^*Korrespondierende*r Autor*in für diese Arbeit

Institut für Organische Chemie

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Abstract

Tetracarbonyl(norbornadiene)chromium(0) was used as complexation reagent in the synthesis of tetracarbonylchromium chelate complexes of dppe, dppb, dppf, DIOP, BINAP, and Tol-BINAP. In all cases the reactions took place under mild reaction conditions with excellent, almost quantitative yields. X-ray crystal structure analyses of the dppf and BINAP tetracarbonylchromium(0) complexes are presented.

Originalsprache	Englisch
Seiten (von - bis)	57-66
Seitenumfang	10
Fachzeitschrift	Arkivoc
Jahrgang	2004
Ausgabenummer	13
Publikationsstatus	Veröffentlicht - 24 Sept. 2004

ASJC Scopus Sachgebiete

Organische Chemie

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title = "High yield synthesis and structures of some achiral and chiral (diphosphine)tetracarbonylchromium(0) chelate complexes with tetracarbonyl(norbornadiene)chromium(0) as complexation reagent",

abstract = "Tetracarbonyl(norbornadiene)chromium(0) was used as complexation reagent in the synthesis of tetracarbonylchromium chelate complexes of dppe, dppb, dppf, DIOP, BINAP, and Tol-BINAP. In all cases the reactions took place under mild reaction conditions with excellent, almost quantitative yields. X-ray crystal structure analyses of the dppf and BINAP tetracarbonylchromium(0) complexes are presented.",

keywords = "BINAP, Chromium complexes, DIOP, dppb, dppe, dppf, Norbornadiene, Tol-binap",

author = "Markus Strotmann and Rudolf Wartchow and Holger Butensch{\"o}n",

year = "2004",

month = sep,

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High yield synthesis and structures of some achiral and chiral (diphosphine)tetracarbonylchromium(0) chelate complexes with tetracarbonyl(norbornadiene)chromium(0) as complexation reagent. / Strotmann, Markus; Wartchow, Rudolf; Butenschön, Holger.
in: Arkivoc, Jahrgang 2004, Nr. 13, 24.09.2004, S. 57-66.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

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T1 - High yield synthesis and structures of some achiral and chiral (diphosphine)tetracarbonylchromium(0) chelate complexes with tetracarbonyl(norbornadiene)chromium(0) as complexation reagent

AU - Strotmann, Markus

AU - Wartchow, Rudolf

AU - Butenschön, Holger

PY - 2004/9/24

Y1 - 2004/9/24

N2 - Tetracarbonyl(norbornadiene)chromium(0) was used as complexation reagent in the synthesis of tetracarbonylchromium chelate complexes of dppe, dppb, dppf, DIOP, BINAP, and Tol-BINAP. In all cases the reactions took place under mild reaction conditions with excellent, almost quantitative yields. X-ray crystal structure analyses of the dppf and BINAP tetracarbonylchromium(0) complexes are presented.

AB - Tetracarbonyl(norbornadiene)chromium(0) was used as complexation reagent in the synthesis of tetracarbonylchromium chelate complexes of dppe, dppb, dppf, DIOP, BINAP, and Tol-BINAP. In all cases the reactions took place under mild reaction conditions with excellent, almost quantitative yields. X-ray crystal structure analyses of the dppf and BINAP tetracarbonylchromium(0) complexes are presented.

KW - BINAP

KW - Chromium complexes

KW - DIOP

KW - dppb

KW - dppe

KW - dppf

KW - Norbornadiene

KW - Tol-binap

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