Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups

Sascha Ceylan; Henry Chun Hin Law; Andreas Kirschning; Patrick H. Toy

doi:10.1055/s-0036-1588589

Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups

Sascha Ceylan
, Henry Chun Hin Law
, Andreas Kirschning^*
, Patrick H. Toy

^*Korrespondierende*r Autor*in für diese Arbeit

University of Hong Kong (HKU)

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Abstract

A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.

Originalsprache	Englisch
Aufsatznummer	ss-2016-z0440-op
Seiten (von - bis)	145-150
Seitenumfang	6
Fachzeitschrift	Synthesis (Germany)
Jahrgang	49
Ausgabenummer	1
DOIs	https://doi.org/10.1055/s-0036-1588589
Publikationsstatus	Veröffentlicht - 3 Jan. 2017

ASJC Scopus Sachgebiete

Katalyse
Organische Chemie

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10.1055/s-0036-1588589

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title = "Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups",

abstract = "A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.",

keywords = "flow chemistry, organocatalysis, phenols, phosphine, polymer-supported catalyst, rearrangement",

author = "Sascha Ceylan and Law, \{Henry Chun Hin\} and Andreas Kirschning and Toy, \{Patrick H.\}",

note = "Funding information: This research was funded in part by the Research Grants Council of the Hong Kong S. A. R., P. R. of China (Project No. HKU 704108P and GHK 031/07), and the Deutscher Akademischer Austauschdienst (DAAD).",

year = "2017",

month = jan,

day = "3",

doi = "10.1055/s-0036-1588589",

language = "English",

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Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups. / Ceylan, Sascha; Law, Henry Chun Hin; Kirschning, Andreas et al.
in: Synthesis (Germany), Jahrgang 49, Nr. 1, ss-2016-z0440-op, 03.01.2017, S. 145-150.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

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AU - Ceylan, Sascha

AU - Law, Henry Chun Hin

AU - Kirschning, Andreas

AU - Toy, Patrick H.

N1 - Funding information: This research was funded in part by the Research Grants Council of the Hong Kong S. A. R., P. R. of China (Project No. HKU 704108P and GHK 031/07), and the Deutscher Akademischer Austauschdienst (DAAD).

PY - 2017/1/3

Y1 - 2017/1/3

N2 - A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.

AB - A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.

KW - flow chemistry

KW - organocatalysis

KW - phenols

KW - phosphine

KW - polymer-supported catalyst

KW - rearrangement

UR - https://www.scopus.com/pages/publications/84991202469

U2 - 10.1055/s-0036-1588589

DO - 10.1055/s-0036-1588589

M3 - Article

AN - SCOPUS:84991202469

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JF - Synthesis (Germany)

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M1 - ss-2016-z0440-op

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