Ready access to bridgehead olefinic isomers of the triquinacene skeleton

Holger Butenschön; Armin de Meijere

doi:10.1016/S0040-4039(00)85956-0

Ready access to bridgehead olefinic isomers of the triquinacene skeleton

Holger Butenschön^*
, Armin de Meijere

^*Korrespondierende*r Autor*in für diese Arbeit

Universität Hamburg

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Abstract

1-Halo- and 1,4-dihalotriquinacenes readily react with secondary amines and alkyl lithium compounds to yield bridgehead olefinic and double bridgehead olefinic derivatives of the tricyclo[5.2.1.0^4'10]decatriene system, probably by an S_N2′ type attack of the soft nucleophile.

Originalsprache	Englisch
Seiten (von - bis)	4563-4566
Seitenumfang	4
Fachzeitschrift	Tetrahedron letters
Jahrgang	24
Ausgabenummer	42
DOIs	https://doi.org/10.1016/S0040-4039(00)85956-0
Publikationsstatus	Veröffentlicht - 1983
Extern publiziert	Ja

ASJC Scopus Sachgebiete

Biochemie
Wirkstoffforschung
Organische Chemie

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10.1016/S0040-4039(00)85956-0

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title = "Ready access to bridgehead olefinic isomers of the triquinacene skeleton",

abstract = "1-Halo- and 1,4-dihalotriquinacenes readily react with secondary amines and alkyl lithium compounds to yield bridgehead olefinic and double bridgehead olefinic derivatives of the tricyclo[5.2.1.04'10]decatriene system, probably by an SN2′ type attack of the soft nucleophile.",

author = "Holger Butensch{\"o}n and \{de Meijere\}, Armin",

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AB - 1-Halo- and 1,4-dihalotriquinacenes readily react with secondary amines and alkyl lithium compounds to yield bridgehead olefinic and double bridgehead olefinic derivatives of the tricyclo[5.2.1.04'10]decatriene system, probably by an SN2′ type attack of the soft nucleophile.

UR - https://www.scopus.com/pages/publications/0348087939

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