Synthesis and characterization of a tricobalt cluster with μ3 tert-butylcarbyne and PSe ligands

Jan Foerstner; Rudolf Wartchow; Holger Butenschön

doi:10.1039/a803784a

Synthesis and characterization of a tricobalt cluster with μ₃ tert-butylcarbyne and PSe ligands

Jan Foerstner^*
, Rudolf Wartchow
, Holger Butenschön

^*Korrespondierende*r Autor*in für diese Arbeit

Institut für Organische Chemie

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Abstract

μ₃-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ₃ tert-butylcarbyn and μ₃ PSe ligands in 48% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.

Originalsprache	Englisch
Seiten (von - bis)	1155-1157
Seitenumfang	3
Fachzeitschrift	New journal of chemistry
Jahrgang	22
Ausgabenummer	11
DOIs	https://doi.org/10.1039/a803784a
Publikationsstatus	Veröffentlicht - 1998

ASJC Scopus Sachgebiete

Katalyse
Allgemeine Chemie
Werkstoffchemie

Zugriff auf Dokument

10.1039/a803784a

Andere Dateien und Links

Link zur Publikation in Scopus

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title = "Synthesis and characterization of a tricobalt cluster with μ3 tert-butylcarbyne and PSe ligands",

abstract = "μ3-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ3 tert-butylcarbyn and μ3 PSe ligands in 48\% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.",

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AB - μ3-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ3 tert-butylcarbyn and μ3 PSe ligands in 48% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.

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