TY - JOUR
T1 - LMU-3
T2 - A new cobalt aluminophosphate with exclusively five-coordinated aluminium and octahedrally coordinated cobalt
AU - Panz, Christian
AU - Polborn, Kurt
AU - Behrens, Peter
N1 - Funding information: We thank A. Glaue and A.M. Schneider (Munich) for their assistance and enlightening discussions as well as G. Wildermuth and J. Felsche (University of Konstanz) for the thermoanalyticai investigations. This work was supported by the Fends der Chemischen Industrie and the Riedel-de Haen-Sit flung.
PY - 1998/4/20
Y1 - 1998/4/20
N2 - A new cobalt aluminophosphate, named LMU-3, has been synthesized from a synthesis mixture containing the 1,1'-dimethylcobalticinium complex cation as a cobalt source. Although the yield of the compound is very low, single crystals can be obtained and a crystal structure analysis has been carried out. The structure of LMU-3 is related to that of a nickel aluminophosphate with the formula K[Ni(H2O)2Al2(PO4)3]. It possesses an open framework built up from distorted [CoO6] octahedra, [AlO5] trigonal byramids and [PO4] tetrahedra. The still somewhat tentative formula for LMU-3 is NH4[Co(H2O)2Al2P3O 12]. It crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.110(2), b=10.163(15), c=8.7424(14) Å, β=108.830(13)°, V=1102.8 Å3 and Z=4. The small amounts of LMU-3 available hamper further characterization.
AB - A new cobalt aluminophosphate, named LMU-3, has been synthesized from a synthesis mixture containing the 1,1'-dimethylcobalticinium complex cation as a cobalt source. Although the yield of the compound is very low, single crystals can be obtained and a crystal structure analysis has been carried out. The structure of LMU-3 is related to that of a nickel aluminophosphate with the formula K[Ni(H2O)2Al2(PO4)3]. It possesses an open framework built up from distorted [CoO6] octahedra, [AlO5] trigonal byramids and [PO4] tetrahedra. The still somewhat tentative formula for LMU-3 is NH4[Co(H2O)2Al2P3O 12]. It crystallizes in the monoclinic space group C2/c (No. 15) with a = 13.110(2), b=10.163(15), c=8.7424(14) Å, β=108.830(13)°, V=1102.8 Å3 and Z=4. The small amounts of LMU-3 available hamper further characterization.
KW - Aluminophosphate complexes
KW - Cobalt complexes
KW - Crystal structures
UR - http://www.scopus.com/inward/record.url?scp=0001930763&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(97)05772-1
DO - 10.1016/S0020-1693(97)05772-1
M3 - Article
AN - SCOPUS:0001930763
SN - 0020-1693
VL - 269
SP - 73
EP - 82
JO - Inorganica chimica acta
JF - Inorganica chimica acta
IS - 1
ER -