Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups

Sascha Ceylan; Henry Chun Hin Law; Andreas Kirschning; Patrick H. Toy

doi:10.1055/s-0036-1588589

Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups

Sascha Ceylan
, Henry Chun Hin Law
, Andreas Kirschning^*
, Patrick H. Toy

^*Corresponding author for this work

University of Hong Kong (HKU)

Research output: Contribution to journal › Article › Research › peer review

Abstract

A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.

Original language	English
Article number	ss-2016-z0440-op
Pages (from-to)	145-150
Number of pages	6
Journal	Synthesis (Germany)
Volume	49
Issue number	1
DOIs	https://doi.org/10.1055/s-0036-1588589
Publication status	Published - 3 Jan 2017

Keywords

flow chemistry
organocatalysis
phenols
phosphine
polymer-supported catalyst
rearrangement

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1055/s-0036-1588589

Cite this

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title = "Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups",

abstract = "A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.",

keywords = "flow chemistry, organocatalysis, phenols, phosphine, polymer-supported catalyst, rearrangement",

author = "Sascha Ceylan and Law, \{Henry Chun Hin\} and Andreas Kirschning and Toy, \{Patrick H.\}",

note = "Funding information: This research was funded in part by the Research Grants Council of the Hong Kong S. A. R., P. R. of China (Project No. HKU 704108P and GHK 031/07), and the Deutscher Akademischer Austauschdienst (DAAD).",

year = "2017",

month = jan,

day = "3",

doi = "10.1055/s-0036-1588589",

language = "English",

volume = "49",

pages = "145--150",

journal = "Synthesis (Germany)",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "1",

}

Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups. / Ceylan, Sascha; Law, Henry Chun Hin; Kirschning, Andreas et al.
In: Synthesis (Germany), Vol. 49, No. 1, ss-2016-z0440-op, 03.01.2017, p. 145-150.

Research output: Contribution to journal › Article › Research › peer review

TY - JOUR

T1 - Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups

AU - Ceylan, Sascha

AU - Law, Henry Chun Hin

AU - Kirschning, Andreas

AU - Toy, Patrick H.

N1 - Funding information: This research was funded in part by the Research Grants Council of the Hong Kong S. A. R., P. R. of China (Project No. HKU 704108P and GHK 031/07), and the Deutscher Akademischer Austauschdienst (DAAD).

PY - 2017/1/3

Y1 - 2017/1/3

N2 - A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.

AB - A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.

KW - flow chemistry

KW - organocatalysis

KW - phenols

KW - phosphine

KW - polymer-supported catalyst

KW - rearrangement

UR - https://www.scopus.com/pages/publications/84991202469

U2 - 10.1055/s-0036-1588589

DO - 10.1055/s-0036-1588589

M3 - Article

AN - SCOPUS:84991202469

SN - 0039-7881

VL - 49

SP - 145

EP - 150

JO - Synthesis (Germany)

JF - Synthesis (Germany)

IS - 1

M1 - ss-2016-z0440-op

ER -

Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups

Abstract

Keywords

ASJC Scopus subject areas

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