Ready access to bridgehead olefinic isomers of the triquinacene skeleton

Holger Butenschön; Armin de Meijere

doi:10.1016/S0040-4039(00)85956-0

Ready access to bridgehead olefinic isomers of the triquinacene skeleton

Holger Butenschön^*
, Armin de Meijere

^*Corresponding author for this work

Universität Hamburg

Research output: Contribution to journal › Article › Research › peer review

Abstract

1-Halo- and 1,4-dihalotriquinacenes readily react with secondary amines and alkyl lithium compounds to yield bridgehead olefinic and double bridgehead olefinic derivatives of the tricyclo[5.2.1.0^4'10]decatriene system, probably by an S_N2′ type attack of the soft nucleophile.

Original language	English
Pages (from-to)	4563-4566
Number of pages	4
Journal	Tetrahedron letters
Volume	24
Issue number	42
DOIs	https://doi.org/10.1016/S0040-4039(00)85956-0
Publication status	Published - 1983
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(00)85956-0

Cite this

@article{c90b51b25a944a609c49f549dc99e452,

title = "Ready access to bridgehead olefinic isomers of the triquinacene skeleton",

abstract = "1-Halo- and 1,4-dihalotriquinacenes readily react with secondary amines and alkyl lithium compounds to yield bridgehead olefinic and double bridgehead olefinic derivatives of the tricyclo[5.2.1.04'10]decatriene system, probably by an SN2′ type attack of the soft nucleophile.",

author = "Holger Butensch{\"o}n and \{de Meijere\}, Armin",

year = "1983",

doi = "10.1016/S0040-4039(00)85956-0",

language = "English",

volume = "24",

pages = "4563--4566",

journal = "Tetrahedron letters",

issn = "0040-4039",

publisher = "Elsevier Ltd.",

number = "42",

}

TY - JOUR

T1 - Ready access to bridgehead olefinic isomers of the triquinacene skeleton

AU - Butenschön, Holger

AU - de Meijere, Armin

PY - 1983

Y1 - 1983

N2 - 1-Halo- and 1,4-dihalotriquinacenes readily react with secondary amines and alkyl lithium compounds to yield bridgehead olefinic and double bridgehead olefinic derivatives of the tricyclo[5.2.1.04'10]decatriene system, probably by an SN2′ type attack of the soft nucleophile.

AB - 1-Halo- and 1,4-dihalotriquinacenes readily react with secondary amines and alkyl lithium compounds to yield bridgehead olefinic and double bridgehead olefinic derivatives of the tricyclo[5.2.1.04'10]decatriene system, probably by an SN2′ type attack of the soft nucleophile.

UR - https://www.scopus.com/pages/publications/0348087939

U2 - 10.1016/S0040-4039(00)85956-0

DO - 10.1016/S0040-4039(00)85956-0

M3 - Article

AN - SCOPUS:0348087939

SN - 0040-4039

VL - 24

SP - 4563

EP - 4566

JO - Tetrahedron letters

JF - Tetrahedron letters

IS - 42

ER -

Ready access to bridgehead olefinic isomers of the triquinacene skeleton

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this