Short-range and long-range magnetic order in Fe(Te1.5Se0.5) O5Cl

E. S. Kozlyakova; K. N. Denisova; A. A. Eliseev; A. V. Moskin; A. Y. Akhrorov; P. S. Berdonosov; V. A. Dolgikh; B. Rahaman; S. Das; T. Saha-Dasgupta; P. Lemmens; A. N. Vasiliev; O. S. Volkova

doi:10.1103/physrevb.102.214405

Short-range and long-range magnetic order in Fe(Te1.5Se0.5) O5Cl

E. S. Kozlyakova
, K. N. Denisova
, A. A. Eliseev
, A. V. Moskin
, A. Y. Akhrorov
, P. S. Berdonosov
, V. A. Dolgikh
, B. Rahaman
, S. Das
, T. Saha-Dasgupta
, P. Lemmens
, A. N. Vasiliev
, O. S. Volkova

Research output: Contribution to journal › Article › Research › peer review

Abstract

Considerable attention has been paid recently to FeTe2O5Cl due to reduced dimensionality and frustration in the magnetic subsystem, succession of phase transitions, and multiferroicity. The efforts to grow its selenite sibling resulted in the mixed halide compound Fe(Te1.5Se0.5)O5Cl, which was found crystallizing in a different structural type and possessing properties drastically different from those of a parent system. Its magnetic subsystem features weakly coupled Fe3+-Fe3+ dimers showing the regime of short-range correlations at TM∼70K and long-range order at TN=22K. In a magnetically ordered state, sizable spin-orbital interactions lead to a small canting of Fe3+ moments. Magnetic dipole-dipole interactions contribute significantly to the experimentally observed orientation of magnetization easy axis in the ac plane. The first principles calculations of leading exchange interactions were found in agreement with measurements of thermodynamic properties and Raman spectroscopy.

Original language	English
Article number	214405
Journal	Physical Review B
Volume	102
Issue number	21
DOIs	https://doi.org/10.1103/physrevb.102.214405
Publication status	Published - 3 Dec 2020
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

Access to Document

10.1103/physrevb.102.214405

Cite this

@article{3f0bc14074b34e1b92fdcde6df4b5805,

title = "Short-range and long-range magnetic order in Fe(Te1.5Se0.5) O5Cl",

abstract = "Considerable attention has been paid recently to FeTe2O5Cl due to reduced dimensionality and frustration in the magnetic subsystem, succession of phase transitions, and multiferroicity. The efforts to grow its selenite sibling resulted in the mixed halide compound Fe(Te1.5Se0.5)O5Cl, which was found crystallizing in a different structural type and possessing properties drastically different from those of a parent system. Its magnetic subsystem features weakly coupled Fe3+-Fe3+ dimers showing the regime of short-range correlations at TM∼70K and long-range order at TN=22K. In a magnetically ordered state, sizable spin-orbital interactions lead to a small canting of Fe3+ moments. Magnetic dipole-dipole interactions contribute significantly to the experimentally observed orientation of magnetization easy axis in the ac plane. The first principles calculations of leading exchange interactions were found in agreement with measurements of thermodynamic properties and Raman spectroscopy.",

author = "Kozlyakova, \{E. S.\} and Denisova, \{K. N.\} and Eliseev, \{A. A.\} and Moskin, \{A. V.\} and Akhrorov, \{A. Y.\} and Berdonosov, \{P. S.\} and Dolgikh, \{V. A.\} and B. Rahaman and S. Das and T. Saha-Dasgupta and P. Lemmens and Vasiliev, \{A. N.\} and Volkova, \{O. S.\}",

note = "Funding Information: This work has been supported by Russian Science Foundation Grant No. 19-42-02010 and by National University of Science and Technology “MISiS” Grant No. K2-2020-008. It was supported also by Act 211 of the Government of Russian Federation, Contracts No. 02.A03.21.0004, No. 02.A03.21.0006, and No. 02.A03.21.0011. P.L. acknowledges support by Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) DFG LE967/16-1 and DFG EXC-2123 QuantumFrontiers 390837967.",

year = "2020",

month = dec,

day = "3",

doi = "10.1103/physrevb.102.214405",

language = "English",

volume = "102",

journal = "Physical Review B",

issn = "2469-9950",

publisher = "American Physical Society",

number = "21",

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T1 - Short-range and long-range magnetic order in Fe(Te1.5Se0.5) O5Cl

AU - Kozlyakova, E. S.

AU - Denisova, K. N.

AU - Eliseev, A. A.

AU - Moskin, A. V.

AU - Akhrorov, A. Y.

AU - Berdonosov, P. S.

AU - Dolgikh, V. A.

AU - Rahaman, B.

AU - Das, S.

AU - Saha-Dasgupta, T.

AU - Lemmens, P.

AU - Vasiliev, A. N.

AU - Volkova, O. S.

N1 - Funding Information: This work has been supported by Russian Science Foundation Grant No. 19-42-02010 and by National University of Science and Technology “MISiS” Grant No. K2-2020-008. It was supported also by Act 211 of the Government of Russian Federation, Contracts No. 02.A03.21.0004, No. 02.A03.21.0006, and No. 02.A03.21.0011. P.L. acknowledges support by Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) DFG LE967/16-1 and DFG EXC-2123 QuantumFrontiers 390837967.

PY - 2020/12/3

Y1 - 2020/12/3

N2 - Considerable attention has been paid recently to FeTe2O5Cl due to reduced dimensionality and frustration in the magnetic subsystem, succession of phase transitions, and multiferroicity. The efforts to grow its selenite sibling resulted in the mixed halide compound Fe(Te1.5Se0.5)O5Cl, which was found crystallizing in a different structural type and possessing properties drastically different from those of a parent system. Its magnetic subsystem features weakly coupled Fe3+-Fe3+ dimers showing the regime of short-range correlations at TM∼70K and long-range order at TN=22K. In a magnetically ordered state, sizable spin-orbital interactions lead to a small canting of Fe3+ moments. Magnetic dipole-dipole interactions contribute significantly to the experimentally observed orientation of magnetization easy axis in the ac plane. The first principles calculations of leading exchange interactions were found in agreement with measurements of thermodynamic properties and Raman spectroscopy.

AB - Considerable attention has been paid recently to FeTe2O5Cl due to reduced dimensionality and frustration in the magnetic subsystem, succession of phase transitions, and multiferroicity. The efforts to grow its selenite sibling resulted in the mixed halide compound Fe(Te1.5Se0.5)O5Cl, which was found crystallizing in a different structural type and possessing properties drastically different from those of a parent system. Its magnetic subsystem features weakly coupled Fe3+-Fe3+ dimers showing the regime of short-range correlations at TM∼70K and long-range order at TN=22K. In a magnetically ordered state, sizable spin-orbital interactions lead to a small canting of Fe3+ moments. Magnetic dipole-dipole interactions contribute significantly to the experimentally observed orientation of magnetization easy axis in the ac plane. The first principles calculations of leading exchange interactions were found in agreement with measurements of thermodynamic properties and Raman spectroscopy.

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DO - 10.1103/physrevb.102.214405

M3 - Article

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SN - 2469-9950

VL - 102

JO - Physical Review B

JF - Physical Review B

IS - 21

M1 - 214405

ER -

Short-range and long-range magnetic order in Fe(Te1.5Se0.5) O5Cl

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QuantumFrontiers: Cluster of Excellence 2123/1: Light and Matter at the Quantum Frontier

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Short-range and long-range magnetic order in Fe(Te1.5Se0.5) O5Cl

Abstract

ASJC Scopus subject areas

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QuantumFrontiers: Cluster of Excellence 2123/1: Light and Matter at the Quantum Frontier

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