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Structure-directed materials syntheses: Metal complexes as structure-directing agents for zeolite-type solids

  • Peter Behrens*
  • , Christian Panz
  • , Volker Hufnagel
  • , Benedikt Lindlar
  • , Clemens C. Freyhardt
  • , Gianpietro Van De Goor
  • *Corresponding author for this work

Research output: Contribution to journalArticleResearchpeer review

Abstract

Metal complexes have been discovered as a novel class of structure-directing agents for the synthesis of porosils, i.e. zeolite-type solids with a pure silica framework. A survey is given about the different preparation methods used and the silica-metal complex host-guest compounds that have been synthesized so far. Special attention is given to differences between cobalticinium nonasil compounds that have been synthesized in basic or fluoride media.

Original languageEnglish
Pages (from-to)229-234
Number of pages6
JournalSOLID STATE IONICS
Volume101-103
Issue numberPART 1
Publication statusPublished - Nov 1997
Externally publishedYes

Keywords

  • Clathrasils
  • Hydrothermal method
  • Structure-directed synthesis
  • Structure-directing agents
  • Zeosils

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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