Subsupercritical Water Generated by Inductive Heating Inside Flow Reactors Facilitates the Claisen Rearrangement

Mona Oltmanns; Andreas Kirschning

doi:10.1055/s-0040-1705945

Subsupercritical Water Generated by Inductive Heating Inside Flow Reactors Facilitates the Claisen Rearrangement

Mona Oltmanns
, Andreas Kirschning^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Research › peer review

Abstract

Claisen rearrangement of electron-deficient O-allylated phenols, including fluorine-modified phenols, is facilitated in aqueous media at high temperatures and pressures under flow conditions, as opposed to organic solvents. The O-allylation of phenols can be coupled with the Claisen rearrangement in an integrated flow system.

Original language	English
Pages (from-to)	1942-1946
Number of pages	5
Journal	SYNLETT
Volume	31
Issue number	19
DOIs	https://doi.org/10.1055/s-0040-1705945
Publication status	Published - 27 Oct 2020

Keywords

Claisen rearrangement
flow chemistry
fluorobenzenes
inductive heating
supercritical water

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0040-1705945

Cite this

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title = "Subsupercritical Water Generated by Inductive Heating Inside Flow Reactors Facilitates the Claisen Rearrangement",

abstract = "Claisen rearrangement of electron-deficient O-allylated phenols, including fluorine-modified phenols, is facilitated in aqueous media at high temperatures and pressures under flow conditions, as opposed to organic solvents. The O-allylation of phenols can be coupled with the Claisen rearrangement in an integrated flow system.",

keywords = "Claisen rearrangement, flow chemistry, fluorobenzenes, inductive heating, supercritical water",

author = "Mona Oltmanns and Andreas Kirschning",

year = "2020",

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AU - Oltmanns, Mona

AU - Kirschning, Andreas

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Y1 - 2020/10/27

N2 - Claisen rearrangement of electron-deficient O-allylated phenols, including fluorine-modified phenols, is facilitated in aqueous media at high temperatures and pressures under flow conditions, as opposed to organic solvents. The O-allylation of phenols can be coupled with the Claisen rearrangement in an integrated flow system.

AB - Claisen rearrangement of electron-deficient O-allylated phenols, including fluorine-modified phenols, is facilitated in aqueous media at high temperatures and pressures under flow conditions, as opposed to organic solvents. The O-allylation of phenols can be coupled with the Claisen rearrangement in an integrated flow system.

KW - Claisen rearrangement

KW - flow chemistry

KW - fluorobenzenes

KW - inductive heating

KW - supercritical water

UR - https://www.scopus.com/pages/publications/85095838695

U2 - 10.1055/s-0040-1705945

DO - 10.1055/s-0040-1705945

M3 - Article

AN - SCOPUS:85095838695

SN - 0936-5214

VL - 31

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JO - SYNLETT

JF - SYNLETT

IS - 19

ER -

Subsupercritical Water Generated by Inductive Heating Inside Flow Reactors Facilitates the Claisen Rearrangement

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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