Suzuki-Miyaura coupling in the presence of (2,2,2-triferrocenylethyl) diphenylphosphane

Jose Ramon Garabatos-Perera; Holger Butenschön

doi:10.1016/j.jorganchem.2007.10.053

Suzuki-Miyaura coupling in the presence of (2,2,2-triferrocenylethyl) diphenylphosphane

Jose Ramon Garabatos-Perera
, Holger Butenschön^*

^*Corresponding author for this work

Institute of Organic Chemistry

Research output: Contribution to journal › Survey paper › Research › peer review

Abstract

The electron rich and sterically bulky title phosphane was prepared and efficiently applied in the palladium catalyzed Suzuki-Miyaura cross-coupling reaction. With electron rich aryl chlorides and bromides the yields and reaction times were significantly improved by microwave heating.

Original language	English
Pages (from-to)	357-360
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	693
Issue number	2
DOIs	https://doi.org/10.1016/j.jorganchem.2007.10.053
Publication status	Published - 15 Jan 2008

Keywords

Cross-coupling
Ferrocene ligands
Palladium
Phosphanes
Suzuki-Miyaura coupling
Triferrocenylmethane

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2007.10.053

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title = "Suzuki-Miyaura coupling in the presence of (2,2,2-triferrocenylethyl) diphenylphosphane",

abstract = "The electron rich and sterically bulky title phosphane was prepared and efficiently applied in the palladium catalyzed Suzuki-Miyaura cross-coupling reaction. With electron rich aryl chlorides and bromides the yields and reaction times were significantly improved by microwave heating.",

keywords = "Cross-coupling, Ferrocene ligands, Palladium, Phosphanes, Suzuki-Miyaura coupling, Triferrocenylmethane",

author = "Garabatos-Perera, \{Jose Ramon\} and Holger Butensch{\"o}n",

note = "Funding information: This work was kindly supported by the Deutsche Forschungsgemeinschaft. We thank Octel Deutschland GmbH for a donation of ferrocene.",

year = "2008",

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day = "15",

doi = "10.1016/j.jorganchem.2007.10.053",

language = "English",

volume = "693",

pages = "357--360",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - Suzuki-Miyaura coupling in the presence of (2,2,2-triferrocenylethyl) diphenylphosphane

AU - Garabatos-Perera, Jose Ramon

AU - Butenschön, Holger

N1 - Funding information: This work was kindly supported by the Deutsche Forschungsgemeinschaft. We thank Octel Deutschland GmbH for a donation of ferrocene.

PY - 2008/1/15

Y1 - 2008/1/15

N2 - The electron rich and sterically bulky title phosphane was prepared and efficiently applied in the palladium catalyzed Suzuki-Miyaura cross-coupling reaction. With electron rich aryl chlorides and bromides the yields and reaction times were significantly improved by microwave heating.

AB - The electron rich and sterically bulky title phosphane was prepared and efficiently applied in the palladium catalyzed Suzuki-Miyaura cross-coupling reaction. With electron rich aryl chlorides and bromides the yields and reaction times were significantly improved by microwave heating.

KW - Cross-coupling

KW - Ferrocene ligands

KW - Palladium

KW - Phosphanes

KW - Suzuki-Miyaura coupling

KW - Triferrocenylmethane

UR - https://www.scopus.com/pages/publications/37348999716

U2 - 10.1016/j.jorganchem.2007.10.053

DO - 10.1016/j.jorganchem.2007.10.053

M3 - Survey paper

AN - SCOPUS:37348999716

SN - 0022-328X

VL - 693

SP - 357

EP - 360

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Suzuki-Miyaura coupling in the presence of (2,2,2-triferrocenylethyl) diphenylphosphane

Abstract

Keywords

ASJC Scopus subject areas

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