Synthesis and characterization of a tricobalt cluster with μ3 tert-butylcarbyne and PSe ligands

Jan Foerstner; Rudolf Wartchow; Holger Butenschön

doi:10.1039/a803784a

Synthesis and characterization of a tricobalt cluster with μ₃ tert-butylcarbyne and PSe ligands

Jan Foerstner^*
, Rudolf Wartchow
, Holger Butenschön

^*Corresponding author for this work

Institute of Organic Chemistry

Research output: Contribution to journal › Article › Research › peer review

Abstract

μ₃-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ₃ tert-butylcarbyn and μ₃ PSe ligands in 48% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.

Original language	English
Pages (from-to)	1155-1157
Number of pages	3
Journal	New journal of chemistry
Volume	22
Issue number	11
DOIs	https://doi.org/10.1039/a803784a
Publication status	Published - 1998

ASJC Scopus subject areas

Catalysis
General Chemistry
Materials Chemistry

Access to Document

10.1039/a803784a

Cite this

@article{e5fe83e21ad748d2905193eec48f4184,

title = "Synthesis and characterization of a tricobalt cluster with μ3 tert-butylcarbyne and PSe ligands",

abstract = "μ3-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ3 tert-butylcarbyn and μ3 PSe ligands in 48\% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.",

author = "Jan Foerstner and Rudolf Wartchow and Holger Butensch{\"o}n",

year = "1998",

doi = "10.1039/a803784a",

language = "English",

volume = "22",

pages = "1155--1157",

journal = "New journal of chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Synthesis and characterization of a tricobalt cluster with μ3 tert-butylcarbyne and PSe ligands

AU - Foerstner, Jan

AU - Wartchow, Rudolf

AU - Butenschön, Holger

PY - 1998

Y1 - 1998

N2 - μ3-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ3 tert-butylcarbyn and μ3 PSe ligands in 48% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.

AB - μ3-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ3 tert-butylcarbyn and μ3 PSe ligands in 48% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.

UR - https://www.scopus.com/pages/publications/0001688019

U2 - 10.1039/a803784a

DO - 10.1039/a803784a

M3 - Article

AN - SCOPUS:0001688019

SN - 1144-0546

VL - 22

SP - 1155

EP - 1157

JO - New journal of chemistry

JF - New journal of chemistry

IS - 11