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Synthesis of Novel Fullerene Complex: the [4+2] Cycloadduct of (Bicyclo[3.2.0]hepta-1,3-dienyl)cobalt(I) Complex with C60

  • Masahiko Iyoda*
  • , Fatema Sultana
  • , Shigeru Sasaki
  • , Holger Butenschön
  • *Corresponding author for this work

Research output: Contribution to journalArticleResearchpeer review

Abstract

The thermal reaction of C60 with (η5-bicyclo[3.2.0]hepta-1,3-dienyl)(η4-tetraphenylcyclobutadiene)cobalt(I) produced the Diels-Alder adducts. The X-ray structural analysis of the 1:1 adduct revealed a novel molecular and crystal structure. An interesting redox behavior of the 1:1 adduct is described.

Original languageEnglish
Pages (from-to)579-582
Number of pages4
JournalTetrahedron letters
Volume36
Issue number4
DOIs
Publication statusPublished - 23 Jan 1995

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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