Tetracyanobutadiene Bridged Push-Pull Chromophores: Development of New Generation Optoelectronic Materials

Yuvraj Patil; Holger Butenschön; Rajneesh Misra

doi:10.1002/tcr.202200208

Tetracyanobutadiene Bridged Push-Pull Chromophores: Development of New Generation Optoelectronic Materials

Yuvraj Patil
, Holger Butenschön^*
, Rajneesh Misra^*

^*Corresponding author for this work

Institute of Organic Chemistry

Indian Institute of Technology Indore (IITI)

Research output: Contribution to journal › Review article › Research › peer review

Abstract

This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.

Original language	English
Article number	e202200208
Number of pages	30
Journal	The chemical record
Volume	23
Issue number	1
DOIs	https://doi.org/10.1002/tcr.202200208
Publication status	Published - 19 Jan 2023

UN Sustainable Development Goals (SDGs)

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 3 Good Health and Well-being

Keywords

Cycloaddition-retroelectrocyclization
Photothermal Therapy
Solar Cells
Tetracyanoethylene

ASJC Scopus subject areas

General Chemistry
Biochemistry
General Chemical Engineering
Materials Chemistry

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10.1002/tcr.202200208Licence: CC BY-NC-ND 4.0

Cite this

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title = "Tetracyanobutadiene Bridged Push-Pull Chromophores: Development of New Generation Optoelectronic Materials",

abstract = "This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.",

keywords = "Cycloaddition-retroelectrocyclization, Photothermal Therapy, Solar Cells, Tetracyanoethylene",

author = "Yuvraj Patil and Holger Butensch{\"o}n and Rajneesh Misra",

note = "Funding Information: We thank the and SERB (Project No. CRG/2018/000032), New Delhi, and DAAD (Leibniz University Hannover and IIT Indore project). R. M. thanks the Alexander von Humboldt Foundation for a research fellowship. Open Access funding enabled and organized by Projekt DEAL. New Passage to India ",

year = "2023",

month = jan,

day = "19",

doi = "10.1002/tcr.202200208",

language = "English",

volume = "23",

journal = "The chemical record",

issn = "1527-8999",

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T1 - Tetracyanobutadiene Bridged Push-Pull Chromophores

T2 - Development of New Generation Optoelectronic Materials

AU - Patil, Yuvraj

AU - Butenschön, Holger

AU - Misra, Rajneesh

N1 - Funding Information: We thank the and SERB (Project No. CRG/2018/000032), New Delhi, and DAAD (Leibniz University Hannover and IIT Indore project). R. M. thanks the Alexander von Humboldt Foundation for a research fellowship. Open Access funding enabled and organized by Projekt DEAL. New Passage to India

PY - 2023/1/19

Y1 - 2023/1/19

N2 - This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.

AB - This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.

KW - Cycloaddition-retroelectrocyclization

KW - Photothermal Therapy

KW - Solar Cells

KW - Tetracyanoethylene

UR - https://www.scopus.com/pages/publications/85139475496

U2 - 10.1002/tcr.202200208

DO - 10.1002/tcr.202200208

M3 - Review article

AN - SCOPUS:85139475496

SN - 1527-8999

VL - 23

JO - The chemical record

JF - The chemical record

IS - 1

M1 - e202200208

ER -

Tetracyanobutadiene Bridged Push-Pull Chromophores: Development of New Generation Optoelectronic Materials

Abstract

UN Sustainable Development Goals (SDGs)

Keywords

ASJC Scopus subject areas

Access to Document

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Cite this