The influence of mafic and felsic crust on the seawater chemistry ca. 3.0 billion years ago: Evidence from Nd isotopes in banded iron formations from the Murchison Greenstone Belt

Banded iron formations (BIFs) are marine chemical sedimentary rocks that serve as prime archives for Precambrian paleo-environmental reconstructions. However, due to the scarcity of well-preserved Archean rocks, the aquatic environments of early Earth remain poorly constrained. In particular, fluxes derived from continents and submarine hydrothermal systems that affected Archean seawater chemistry are crucial for the understanding of the evolution of marine environments. To fill this gap, we present major- and trace element data in combination with Sm-Nd isotopes of individual BIF layers from the ca. 3.0 Ga old Murchison Greenstone Belt (MGB) of South Africa. BIF layers with low immobile element concentrations show seawater-like shale-normalized (subscript SN) rare earth and yttrium (REY _SN) patterns with heavy over light REY _SN enrichment and positive La _SN, Eu _SN, Gd _SN, and Y _SN anomalies, implying an anoxic marine depositional setting with contributions from high-temperature, hydrothermal systems. These BIF samples yield a Sm-Nd age of 2993 ± 97 Ma that overlaps with the proposed depositional age suggesting negligible post-depositional alteration. In contrast, BIF layers with non-seawater-like REY _SN patterns yield a Sm-Nd age of 2504 ± 161 Ma, which can be linked to post-depositional alteration during the ca. 2.7 Ga Limpopo orogeny. The range of initial εNd values from −1.74 to + 0.15 in pristine BIF samples suggests that elements of mixed juvenile and evolved material from emerged continents and/or hydrothermal systems affected Murchison seawater and indicates potential oceanic water mixing in the Murchison region with water masses derived from the northern Pietersburg and the southern Kaapvaal regions.